Right after charge stability is accomplished the gypsum content material is decided and taken off. The removal of equimolar contents of calcium and sulfate follows the idea that gypsum is mostly existing in crystalline sort, which is necessary with the input date of ECOS/Runsalt. Consequently, it is actually acceptable to evaluate the balance involving the two ions (just after Eqs. 4 and five), as illustrated in Fig. three. All sulfate and calcium ions not balanced, respectively ideal and remaining while in the figure, aren't connected with gypsum and belong to different mixture styles.
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The calculation gets rid of the charge distinction between ions and allows direct comparison involving cation and anion equilibrium:
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This worth was chosen to eradicate rounding faults without the need of implications to facts interpretation. The anion and cation values soon after removal on the theoretical gypsum information as more info mole fraction (xi,adj) is decided by:
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